Synthesis, characterization and thermal behaviour of solid-state compounds of 4-methoxybenzoate with lanthanum (III) and trivalent lighter lanthanides
PDF (English)

Palavras-chave

lighter lanthanides
4-methoxybenzoate
characterization
thermal behaviour

Como Citar

Rodrigues, Érica A. C., de Siqueira, A. B., Ionashiro, E. Y., Bannach, G., & Ionashiro, M. (2006). Synthesis, characterization and thermal behaviour of solid-state compounds of 4-methoxybenzoate with lanthanum (III) and trivalent lighter lanthanides. Eclética Química, 31(1), 21–30. https://doi.org/10.26850/1678-4618eqj.v31.1.2006.p21-30

Resumo

Solid-state M-4-MeO-Bz compounds, where M stands for trivalent La, Ce, Pr, Nd and Sm and
4-MeO-Bz is 4-methoxybenzoate, have been synthesized. Simultaneous thermogravimetry and differential
thermal analysis (TG-DTA), differential scanning calorimetry (DSC), X-ray powder diffractometry,
infrared spectroscopy and complexometry were used to characterize and to study the thermal behaviour of
these compounds. The results led to information about the composition, dehydration, polymorphic trans-
formation, ligand’s denticity, thermal behaviour and thermal decomposition of the isolated compounds.
https://doi.org/10.26850/1678-4618eqj.v31.1.2006.p21-30
PDF (English)

Referências

S. J. Yun, S. K. Kang, S. S. Yun, Thermochim. Acta 331(1)

(1999) 13.

Z. M. Wang, L. J. Van de Burgt, G. R. Choppin, Inorg.

Chim. Acta 167 (1999) 293.

N. Arnaud, J. Georges Analyst, 125 (8) (2000) 1487.

G. R. Choppin, P. A. Bertrand, Y. Hasegawa, N. Rizalla,

Inorg. Chem. 21 (10) (1982) 3722.

A. W. H. Lam, W. T. Wang, S. Gao, G. Wen, X. X. Zhang,

Eu. J. Inorg. Chem. (1) (2003) 149.

W. W. Wendlandt. Anal. Chim. Acta. 17(3) (1957) 295.

W. W. Wendlandt. Anal. Chem. 29(5) (1957) 800.

A. K. J. Galwey, J. Chem. Society 1152 (1965) 6188.

S. B. Pirkes, G. N. Makushova, A. V. Lapitskaya, Russian

J. Inorg. Chem. 21 (1976) 661.

S. B. Pirkes, A. V. Lapitskaya, G. N. Makushova,

Russian J. Inorg. Chem. 21 (1976) 816.

G. N. Makushova, A. V. Lapitskaya, S. O. Goppe, S. B.

Pirkes, Russian J. Inorg. Chem. 24 (1979) 1574.

S. B. Pirkes, G. N. Makushova, A. V. Lapitskaya, N. P.

Tsilina, Russian J. Inorg. Chem. 28 (1983) 1684.

G. N. Makushova, S. B. Pirkes, Russian J. Inorg. Chem.

(1984) 531.

G. N. Makushova, S. B. Pirkes, E. Yu. Levina, Russian

J. Inorg. Chem. 30 (1985) 652.

G. N. Makushova, S. B. Pirkes, E. Yu. Levina, Zhurnal

Neorganicheskoi Khimii 30 (9) (1985) 2273.

G. N. Makushova, S. B. Pirkes, J. Inorg. Chem. 32

(1987) 489.

W. Lewandowski, J. Molec. Strut. 101 (1-2) (1983) 93.

W. Lewandowski, H. Baranska, J. Raman Spectroscopy

(1) (1986) 17.

T. Glowiak, H. Kozlowski, L. Strinna Erre, B. Gulinati,

G. Micera, A. Pozzi, S. Brunni, J. Coord. Chem. 25 (1992) 75.

W. Brzyska, S. Karasinski, J. Thermal Anal. 39 (1993) 429.

W. Ferenc, B. Bocian, J. Thermal Anal. Cal. 62 (3)

(2000) 831.

B. Bocian, B. Czajka, W. Ferenc, J. Thermal Anal. Cal.

(3) (2001) 729.

B. Czajka, B. Bocian, W. Ferenc, J. Thermal Anal. Cal.

(3) (2002) 631.

W. Ferenc, B. Bocian, J. Thermal Anal. Cal. 74 (2)

(2003) 521.

W. Ferenc, A. Walkow-Dziewulska, J. Thermal Anal.

Cal. 71 (2) (2003) 375.

N. S. Fernandes, M. A. S. Carvalho Filho, C. B. Melios,

M. Ionashiro, J. Thermal Anal. Cal. 73 (1) (2003) 307.

N. S. Fernandes, M. A. S. Carvalho Filho, R. A. Mendes,

C. B. Melios, M. Ionashiro, J. Thermal Anal. Cal. 76 (1)

(2004) 193.

W. Ferenc, B. Bocian, A. Walków-Dziewulska, J.

Thermal Anal. Cal. 76 (1) (2004) 179.

E. C. Rodrigues, A. B. Siqueira, E. Y. Ionashiro, G.

Bannach, M. Ionashiro, J Thermal Anal. Cal. 79 (2005) 323.

H. A. Flaschka, EDTA Titrations; Pergamon Press;

Oxford, 1964.

M. Ionashiro, C. A. F. Graner, J. Zuanon Netto, Ecl.

Quim. 8 (1983) 29.

T. H. Dunning Jr, P. J. Hay, Modern Theoretical

Chemistry, Ed. H. F. Schaefer; New York; 1976, pp. 1-28.

P. J. Hay, W. R. Wadt, J. Chem. Phys. 82 (1) (1985) 270.

W. R. Wadt, P. J. Hay, J. Chem. Phys. 82 (1) (1985) 284.

P. J. Hay, W. R. Wadt, J. Chem. Phys. 82 (1) (1985) 299.

C. C. J. Roothan, Rev. Mod. Phys. 23 (1951) 69.

M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria,

M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A.

Montgomery, Jr., R. E. Stratmann, J. C. Burant, S. Dapprich, J.

M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas,

J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C.

Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P.

Y. Ayala, Q. Cui, K. Morokuma, N. Rega, P. Salvador, J. J.

Dannenberg, D. K. Malick, A. D. Rabuck, K. Raghavachari, J.

B. Foresman, J. Cioslowski, J. V. Ortiz, A. G. Baboul, B. B.

Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R.

Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C.

Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B.

Johnson, W. Chen, M. W. Wong, J. L. Andres, C. Gonzalez, M.

Head-Gordon, E. S. Replogle, J. A. Pople, Gaussian 98,

Revision A.11.2. Gaussian, Inc., Pittsburgh PA, 2001.

G. Socrates, Infrared Characteristic Group Frequencies,

Wiley; New York, 2nd ed. 1994, pp.91 and 236-237.

R. M. Silverstein, F. X. Webster, Spectrometric

Identification of Organic Compounds, Wiley, New York, 6th

ed., 1998, pp. 92, 93, 96 and 97.

W. Lewandowsky, H. Baranska, J. Raman Spect. 17 (1)

(1986) 17.

D. Z. Goodson, S. K. Sarpal, Phlilppe Bopp, M.

Wolfsberg, J. Phys. Chem., 86 (1982) 659.

H. B. Schelegel. In new theoretical concepts for under-

standing organic reaction. J. Berdron Ed., Academic: The

Netherlands; 1989, pp 33-53.

Creative Commons License
Este trabalho está licenciado sob uma licença Creative Commons Attribution 4.0 International License.

Copyright (c) 2018 Eclética Química

Métricas

Carregando Métricas ...