Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π–π stacking interactions
PDF (English)

Palavras-chave

copper complex
crystal structure
supramolecular
π-π interaction

Como Citar

Li, X.-H., Jalbout, A. F., & Xiang, W. D. (2008). Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π–π stacking interactions. Eclética Química, 33(2), 13–19. https://doi.org/10.26850/1678-4618eqj.v33.2.2008.p13-19

Resumo

A new Cu(II) trimers, [Cu3(dcp)2(H2O)8]. 4DMF, with the ligand 3,5-pyrazoledicarboxylic acid monohydrate (H3dcp) has been prepared by solvent method. Its solid-state structure has been characterized by elemental analysis, thermal analysis (TGA and DSC), and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this complex has extended 1-D,2-D and 3-D supramolecular architectures directed by weak interactions (hydrogen bond and aromatic π-π stacking interaction) leading to a sandwich solid-state structure.
https://doi.org/10.26850/1678-4618eqj.v33.2.2008.p13-19
PDF (English)

Referências

T.K. Maji, K. Uemura, H.-C. Chang, R. Matsuda, S. Kitagawa, Angew. Chem. Int. Ed. 43 (2004) 3269.

F.A. Cotton, C. Lin, C.A. Murillo, Acc. Chem. Res. 34

(2001) 759.

A. Morsali, A.R. Mahjoub, Polyhedron 23 (2004) 2427.

S. Kawata, S. Kitagawa, H. Kumagai, C. Kudo, H. Kamesaki, T. Ishiyama, R. Suzuki, M. Kondo, M. Katada, Inorg. Chem. 35 (1996) 4445.

O.M. Yaghi, C.E. Davis, G. Li, H. Li, J. Am. Chem. Soc. 119 (1997) 2861.

D. Dobrzyjska, T. Lis, L.B. Jerzykiewicz, Inorg. Chem.

Commun. 8 (2005) 1090.

J.P. GarcÌa-Ter·n, O. Castillo, A. Laque, U. Garcia-Couceivo, P. Rom·n, F. Lloret, Inorg. Chem. 43 (2004) 5761.

A.M. Chippindale, M.R. Grimshaw, A.V. Powell, A.R. Cowley, Inorg. Chem. 44 (2005) 4121.

S.J. Loeb, Chem. Commun. (2005) 1511.

T.K. Maji, G. Mostafa, H.-C. Chang, S. Kitagawa, Chem.

Commun. (2005) 2439.

O.M. Yaghi, H. Li, J. Am. Chem. Soc. 118 (1996) 295.

Q. Wei, M. Nieuwenhuyzen, F. Meunier, C. Hardacre,

S.L. James, J. Chem. Soc. Dalton Trans. (2004) 1807.

A.R. Millward, O.M. Yaghi, J. Am. Chem. Soc. 127

(2005) 17998.

B.J. Holliday, C.A. Mirkin, Angew. Chem. Int. Ed. 40

(2001) 2022.

P.J. Hagraman, D. Hagrman, J. Zubieta, Angew. Chem.

Int. Ed. 38 (1999) 2638.

G. R. Desiraju, Angew Chem. Int. Ed. Engl. 34 (1995) 2311.

G. R. Desiraju, Chem. Commun. (1997)1475.

D. Braga, F. Grepioni, G. R. Desiraju, Chem. Rev. 98

(1998) 1375.

D. Braga, F. Grepioni, Acc. Chem. Res. 33 (2000) 601.

M. J. Zaworotko, Nature (London), 386 (1997) 220.

S.-I. Noro, H. Miyasaka, S. Kitagawa, T. Wada, T.

Okubo, M. Yamashita, T. Mitani, Inorg. Chem. 44 (2005) 133.

P. Diaz, J. Benet-Buchholz, R. Vilar, A.J.P. White, Inorg.

Chem. 45 (2006) 1617.

F.S. Delgado, J. Sanchiz, C. Ruiz-PÈrez, F. Lloret, M.

Julve, Inorg. Chem. 42 (2003) 5938.

H.W. Roesky, M. Andruh, Coord. Chem. Rev. 236 (2003) 91.

E. Colacio, F. Lloret, R. Kivekäs, J. Ruiz, J. Suärez-

Varela, M.R. Sunberg, Chem. Commun. (2002) 592.

Pan. L, Ching. N, Huang. X, Li. J. Chem. Eur. J. 7 (2001)

- 4437.

Wenkin. M, Devillers. M, Tinant. B, Declercq. J. Inorg.

Chim. Acta 258 (1997) 113-118.

Sanna. D, Micera. G, Buglyo. P, Kiss. T, Gajda. T, Surdy. P. Inorg. Chim. Acta 268 (1998) 297-305.

Sakagami. N, Nakahanada. M, Ino. K, Hioki. A, Kaizaki.

S. Inorg. Chem. 35 (1996) 683-688.

Nakahanada. M, Ino. K, Kaizaki. S. J. Chem. Soc., Dalton Trans. (1993) 3681-3684.

G. M. Sheldrick, SHELXTLVersion 5, Siemens, Industrial

Automation Inc., Madison, Wisconsin, U. S. A., 1995.

G.M. Sheldrick, SHELXK97, Programs for Crystal Structure Analysis, University of Go¨ttingen, Germany, 1997.

Philippa King, Rodolphe Cle´rac, Christopher E. Anson,

Claude Coulon, and Annie K. Powell, Inorg. Chem. 42 (2003)

-3500.

Creative Commons License
Este trabalho está licenciado sob uma licença Creative Commons Attribution 4.0 International License.

Copyright (c) 2018 Eclética Química

Métricas

Carregando Métricas ...