Eletrocatálise da reação de redução de oxigênio sobre eletrodos de grafite modificados com ftalocianina tetracarboxilada de ferro §
Article Sidebar
Main Article Content
Abstract
modificados, em níveis de monocamadas, com ftalocianina tetracarboxilada de ferro, FeTcPc, em soluções
aquosas. Em meio alcalino, os eletrodos modificados apresentaram alta atividade eletrocatalítica para a
reação de redução de oxigênio, comparável com a do eletrodo de platina. A reação processa-se de acordo
com uma cinética de primeira ordem com relação ao oxigênio dissolvido, um mecanismo envolvendo 4
elétrons e associado com o processo redox Fe(3+)TcPc/Fe(2+)TcPc.
Metrics
Article Details
This work is licensed under a Creative Commons Attribution 4.0 International License.
The corresponding author transfers the copyright of the submitted manuscript and all its versions to Eclet. Quim., after having the consent of all authors, which ceases if the manuscript is rejected or withdrawn during the review process.
When a published manuscript in EQJ is also published in other journal, it will be immediately withdrawn from EQ and the authors informed of the Editor decision.
Self-archive to institutional, thematic repositories or personal webpage is permitted just after publication. The articles published by Eclet. Quim. are licensed under the Creative Commons Attribution 4.0 International License.
References
N. M. Markovic, P.N. Ross. Electrocatalysis at well-defined
surfaces: kinetics of oxygen reduction and hydrogen oxidation/
evolution on Pt(hkl) electrodes. In: Wieckowski, A. Interfacial
Electrochemistry – Theory, Experiments and Applications. New
York: Marcel Dekker, 1999. 992p, 821-841.
R. R. Adzic. Recent Advances in the Kinetics of Oxygen
Reduction. In: LIPKOWSKI, J., ROSS, P. N. Electrocatalysis.
New York, Wiley-VCH, 1998, pp.197-242.
K. Kinoshita. Electrochemical Oxygen Technology. New
York, Wiley-Interscience, 1992, 448p.
M. R. Tarasevich, A. Sadkowski, E. Yeager. Oxygen
electrochemistry. In: Conway, B. E., Bockris, J. O’M., Yeager,
E., Khan, S. U. M., White, R. E.. Comprehensive Treatise in
Electrochemistry. New York, Plenum Press, 1983, pp.301-398.
U. A. Paulus, A. Wokaun, G. G. Scherer, T. J. Schmidt, V.
Stamenkovi, N. M. Markovic, P. N., Ross. Electrochimica Acta 47 (2002) 3787.
S. C. Thomas, X. M. Ren, S. Gottesfeld, P. Zelenay.
Electrochimica Acta 46 (2002) 3741.
C. Lamy, A. Lima, V. Lerhun, F. Delime, C. Countanceau,
J. M. LegeR. Journal of Power Sources 105 (2002) 283.
P. Costamagna, S. Srinivasan. Journal of Power Sources
(2001) 242.
T. J. P. Freire, E. R. Gonzalez. Journal of Electroanalytical
Chemistry 503 (2001) 57.
M. T. Giacomini, E. A. Ticianelli, J. McBreen,
M.Salasubramanian. Journal of The Electrochemical Society
(2001) A323.
A. J. McEvoy. Journal of Material Science 36 (2001) 1087.
A. A. Tanaka, R. Adzic, B. Nikolic. Jounal of Serbian
Chemistry Society 64 (1999) 695.
M. Calegaro, J. Perez, A. A. Tanaka, E. A. Ticianelli, E.
Gonzalez. Denki Kagaku 64 (1996) 436.
S. A. S. Machado, A. A. Tanaka, E. Gonzalez. Electrochimica Acta 39 (1994) 2591.
J. Perez, A. A. Tanaka, E. Gonzalez, E. A. Ticianelli.
Journal of The Electrochemical Society 141 (1994) 431.
J. H. Zagal. Coordination Chemistry Reviews 119 (1992) 89.
P. Vasudevan, H. Santosh, N. Mann, S. Tyagi. Transition
Metal Chemistry 15 (1990) 81.
M. R. Tarasevich, K. A. Radyushkina. Russian Chemical
Reviews 49 (1980)718-730.
N. Zheng, Y. Zeng, P. G. OsbornE, Y. Li, W. Chang, Wang.
Journal of Applied Electrochemistry 32 (2002) 129.
G. Ramirez, E. Trollund, M. Isaacs, F.Rmijo, J. Zagal, J.
Costamagna, M. J. Aguirre. Electroanalysis 14 (2002) 540.
S. L. P. Dias, Y. Gushikem, E. S. Ribeiro, E. V. Benvenutti.
Journal of Electroanalytical Chemistry 523 (2002) 64.
M. Ebadi, C. Lexiou, A. B. P. Lever. Canadian Journal of
Chemistry 79 (2001) 992.
R. P. Alves, C. D. C. Conceição, J. A. Chaves, A. A.
Tanaka. Anais da Associação Brasileira de Química 49
(1)(2000) 46.
E. H. Song, C. N. Shi, F. C. Anson. Langmuir 14 (1998) 4315.
A. Biloul, P. Gouerec, M. Savy, G.Carbeck, S. Besse, J.
Riga. Journal of Applied Electrochemistry 26 (1996) 1139.
N. Phougat, P. Vasudevan. Journal of Power Sources 69
(1997) 161.
J. H. Zagal, M. Paez, A. A. Tanaka, J. R. Santos Junior, C.
Linkous. Journal of Electroanalytical Chemistry 339 (1-
(1992) 13.
A. A. Tanaka, C. Fierro, D. A. Scherson, E. Yeager.
Material Chemistry and Physics 22 (3-4)(1989) 431.
A. A. Tanaka, C. Fierro, D. Scherson, E. Yeager. Journal
of Physical Chemistry 91 (14)(1987) 3799.
A. van der Putten, A. Elzing, W. Visscher, E. Barendrecht.
Journal of Electroanalytical Chemistry 214 (1-2)(1986) 523.
S. Zecevic, B. Simic-Glavaski, E. Yeager, A. B. P. Lever,
P. C. Minor. Journal of Electroanalytical Chemistry 196
(2)(1985) 339.
N. Kobayashi, Y. Nishiyama. Journal of Physical
Chemistry 89(1985) 1167.
J. H. Zagal, P. Bindra, Yeager, E. Journal of The
Electrochemical Society 127 (7)(1980) 1506.
J. P. Collman, P. DENISEVICH, Y. Konai, M. Marrocco,
C. Koval, F. C. Anson. Journal of The American Chemical
Society 102 (1980) 6027.
A. J. Appleby, J. Fleisch, M. Savy. .Journal of Catalysis
(2)(1976) 281.
K. Kinoshita. Carbon: Electrochemical and
Physicochemical Properties. New York. Wiley-Interscience,
533p.
D. D. Perrin, B. Dempsey. Buffers for pH and Metal Ion
Control. New York: Chapman and Hall, 1974. 171p.
K. D. Snell, A. G. Keenan. Chemical Society Reviews 8
(1979) 259.
M. S. R. Nahuz, A. P. Reis, M. F. A. Araújo, A. A. Tanaka.
Influências das Orientações Basal e Edge e do Pré-Tratamento
Superficial nas Propriedades Eletroquímicas de Eletrodos de
Grafite Pirolítico Modificados com Ftalocianina de Cobalto”,
Cadernos de Pesquisa da Universidade Federal do Maranhão,
v.11 (1), p.65-74, 2000.
A. J. Bard, L. R. Faulkner. Electrochemical methods. New
York: John Wiley & Sons, 1980. 718p.
R. S. Nicholson, I. Shain. Analytical Chemistry 36
(4)(1964) 706.
K. E. Gubbins, R. D. Walker. Journal of The
Electrochemical Society 112 (5)(1965) 469.
R. E. Davis, G. L. Horvath, C. W. Tobias. Electrochimica
Acta 12 (3)(1967) 287.
J. J. Zhang, F. C. Anson. Journal of Electroanalytical
Chemistry 341 (1-2)(1992) 323.
J.Koutecky, B. G. Levich. Zhurnal Fizicheskoi Khimii 32
(7)(1958) 1565.
B. G. Levich. Physicochemical Hydrodynamics.
Englewood Cliffs – NJ: Prentice Hill, 1962, p.345.