Efeito do tipo e tempo de agitação na atividade catalítica de rutenioporfirina
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Abstract
Neste trabalho, o complexo (carbonil)[tetrakis(5,10,15,20-ortobromofenil)porfirinato]rutênio(II) foi sintetizado e estudado como catalisador na oxidação de cicloexano por iodosilbenzeno. Em tal estudo variou-se as condições do sistema a fim de se verificar o melhor tempo e meio de agitação (mecânica e/ou sonicação). Os resultados demonstram boa eficiência, seletividade e regeneração do catalisador quando se utiliza um sistema misto de agitação.
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