Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π–π stacking interactions

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Published: Jun 23, 2008
DOI: https://doi.org/10.26850/1678-4618eqj.v33.2.2008.p13-19
Keywords:
copper complex, crystal structure, supramolecular, π-π interaction

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Xin-Hua Li
Wenzhou University, College of Chemistry and Materials Engineering, Wenzhou, China.
Abraham F. Jalbout
Universidad Nacional Autónoma de México, Instituto de Química, Ciudad de México, Mexico.
Wei Dong Xiang
Wenzhou University, College of Chemistry and Materials Engineering, Wenzhou, China.

Abstract

A new Cu(II) trimers, [Cu3(dcp)2(H2O)8]. 4DMF, with the ligand 3,5-pyrazoledicarboxylic acid monohydrate (H3dcp) has been prepared by solvent method. Its solid-state structure has been characterized by elemental analysis, thermal analysis (TGA and DSC), and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this complex has extended 1-D,2-D and 3-D supramolecular architectures directed by weak interactions (hydrogen bond and aromatic π-π stacking interaction) leading to a sandwich solid-state structure.

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How to Cite
Li, X.-H., Jalbout, A. F., & Xiang, W. D. (2008). Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π–π stacking interactions. Eclética Química, 33(2), 13–19. https://doi.org/10.26850/1678-4618eqj.v33.2.2008.p13-19
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Vol. 33 No. 2 (2008): Eclética Química
Section
Original articles
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