Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π–π stacking interactions
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Keywords

copper complex
crystal structure
supramolecular
π-π interaction

How to Cite

Li, X.-H., Jalbout, A. F., & Xiang, W. D. (2008). Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π–π stacking interactions. Eclética Química, 33(2), 13–19. https://doi.org/10.26850/1678-4618eqj.v33.2.2008.p13-19

Abstract

A new Cu(II) trimers, [Cu3(dcp)2(H2O)8]. 4DMF, with the ligand 3,5-pyrazoledicarboxylic acid monohydrate (H3dcp) has been prepared by solvent method. Its solid-state structure has been characterized by elemental analysis, thermal analysis (TGA and DSC), and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this complex has extended 1-D,2-D and 3-D supramolecular architectures directed by weak interactions (hydrogen bond and aromatic π-π stacking interaction) leading to a sandwich solid-state structure.
https://doi.org/10.26850/1678-4618eqj.v33.2.2008.p13-19
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