Synthesis and characterization of SiO2 from Madura Strait sediment with leaching acid treatment
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Keywords

amorphous structure
Madura Strait sediment
natural source
adsorption properties
impurity removal

How to Cite

Hidayat, A., Wijaya, A. R., & Kusumaningrum, I. K. (2026). Synthesis and characterization of SiO2 from Madura Strait sediment with leaching acid treatment. Eclética Química, 51, e–1577. https://doi.org/10.26850/1678-4618.eq.v51.2026.e1577

Abstract

Silicon dioxide (SiO₂) was successfully synthesized from Madura Strait sediment. The production process involved a wet digestion step using a strong acid to decompose the sample. Subsequent calcination and purification with strong acid effectively removed impurities, yielding a white sedimentary material. The synthesized SiO₂ was characterized using X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). After impurity removal, the silicon content in the raw sediment increased from 33.5% to 83.3%. XRD analysis confirmed the successful formation of amorphous SiO₂ particles. FTIR spectra indicated the presence of Si–O–Si and Si–OH functional groups, representing silanol and siloxane structures. SEM analysis revealed that the SiO₂ particles formed aggregates with an irregular arrangement, where individual particles appeared loosely associated.

https://doi.org/10.26850/1678-4618.eq.v51.2026.e1577
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References

Azlina, H. N.; Hasnidawani, J. N.; Norita, H.; Surip, S. N. Synthesis of SiO2 Nanostructures Using Sol-Gel Method. Acta Phys. Pol. A. 2016, 129 (4), 842–844. https://doi.org/10.12693/APhysPolA.129.842

Chu, C.-Y.; Ko, T.-H. Evaluation of Acid Leaching on the Removal of Heavy Metals and Soil Fertility in Contaminated Soil. J. Chem. 2018, 2018, 1–8. https://doi.org/10.1155/2018/5036581

Davis, B. L.; Kath, R.; Spilde, M. The Reference Intensity Ratio: Its Measurement and Significance. Powder Diffr. 1990, 5 (2), 76–78. https://doi.org/10.1017/S0885715600015372

Dubey, R. S.; Rajesh, Y. B. R. D.; More, M. A. Synthesis and Characterization of SiO2 Nanoparticles via Sol-Gel Method for Industrial Applications. Mater. Today Proc. 2015, 2 (4–5), 3575–3579. https://doi.org/10.1016/j.matpr.2015.07.098

Fatimah, S.; Ragadhita, R.; Husaeni, D. F. Al; Nandiyanto, A. B. D. How to Calculate Crystallite Size from X-Ray Diffraction (XRD) Using Scherrer Method. ASEAN Journal of Science and Engineering. 2021, 2 (1), 65–76. https://doi.org/10.17509/ajse.v2i1.37647

Griscom, D. L. The Natures of Point Defects in Amorphous Silicon Dioxide. In: Defects in SiO2 and Related Dielectrics: Science and Tecnology. Paccioni, G.; Skuja,L.;Griscom, D. L. (Eds.). NATO Science Series, Series II: Mathematical and Physical Chemistry - Vol. 2, IOS Press, Amsterdam, 2000. https://doi.org/10.1007/978-94-010-0944-7_4

Hosseini, S. M.; Askari, M.; Koranian, P.; Madaeni, S. S.; Moghadassi, A. R. Fabrication and Electrochemical Characterization of PVC Based Electrodialysis Heterogeneous Ion Exchange Membranes Filled with Fe3O4 Nanoparticles. Journal of Industrial and Engineering Chemistry. 2014, 20 (4), 2510–2520. https://doi.org/10.1016/j.jiec.2013.10.034

Ishmah, S. N.; Permana, M. D.; Firdaus, M. L.; Eddy, D. R. Extraction of Silica from Bengkulu Beach Sand Using Alkali Fusion Method. PENDIPA Journal of Science Education. 2020, 4 (2), 1–5. https://doi.org/10.33369/pendipa.4.2.1-5

Li, C.; Ma, C.; Wang, F.; Xi, Z.; Wang, Z.; Deng, Y.; He, N. Preparation and Biomedical Applications of Core-Shell Silica/Magnetic Nanoparticle Composites. Journal of Nanoscience and Nanotechnology. 2012, 12 (4), 2964–2972. https://doi.org/10.1166/jnn.2012.6428

Munasir; Triwikantoro; Zainuri, M.; Darminto. Synthesis of SiO2 Nanopowders Containing Quartz and Cristobalite Phases from Silica Sands. Materials Science-Poland. 2015, 33 (1), 47–55. https://doi.org/10.1515/msp-2015-0008

Nandanwar, R.; Singh, P.; Haque, F. Synthesis and Characterization of SiO2 Nanoparticles by Sol-Gel Process and Its Degradation of Methylene Blue. American Chemical Science Journal. 2015, 5 (1), 1-10. https://doi.org/10.9734/ACSJ/2015/10875

Nandiyanto, A. B. D.; Oktiani, R.; Ragadhita, R. How to Read and Interpret FTIR Spectroscope of Organic Material. Indonesian Journal of Science and Technology. 2019, 4 (1), 97-118. https://doi.org/10.17509/ijost.v4i1.15806

Nikmah, A.; Taufiq, A.; Hidayat, A. Synthesis and Characterization of Fe3O4/SiO2 Nanocomposites. IOP Conf Ser Earth Environ Sci. 2019, 276 (1) 012046. https://doi.org/10.1088/1755-1315/276/1/012046

Saikumari, N.; Dev, S. M.; Dev, S. A. Effect of Calcination Temperature on The Properties and Applications of Bio Extract Mediated Titania Nanoparticles. Sci. Rep. 2021, 11 (1), 1–17. https://doi.org/10.1038/s41598-021-80997-z

Suci, C. W.; Wijaya, A. R.; Santoso, A.; Kusumaningrum, I. K. Fe leaching in the sludge sediment of the Prigi beach with Tessier-Microwave method. In AIP Conference Proceedings; American Institute of Physics Inc., 2020; Vol. 2231, p 040025. https://doi.org/10.1063/5.0002589

Trivana, L.; Sugiarti, S.; Rohaeti, E. Sintesis Dan Karakterisasi Natrium Silikat (NA2SIO3) Dari Sekam Padi. Jurnal Sains & Teknologi Lingkungan. 2015, 7 (2), 66–75. https://doi.org/10.20885/jstl.vol7.iss2.art1

Wang, L.; Wang, Z.; Yang, H.; Yang, G. The Study of Thermal Stability of the SiO2 Powders with High Specific Surface Area. Mater. Chem. Phys. 1999, 57 (3), 260–263. https://doi.org/10.1016/S0254-0584(98)00226-0

Wijaya, A. R.; Farida, I.; Sakbaniah, A.; Rahmawati, A. M.; Budiasih, E.; Daupor, H.; et al. Distribution and Assessment of Fe and Mn in the Coastal Sediments of Sendang Biru, East Java, Indonesia. Journal of Physics: Conference Series 2018a, 1093(1), 012013. https://doi.org/10.1088/1742-6596/1093/1/012013

Wijaya, A. R.; Farida, I.; Wonorahardjo, S.; Utomo, Y.; Daupor, H.; Hossain, Md. S.; et al. BCR Sequential Leaching for Geochemical Fractions and Assessment of Fe, Ni, and Mn in the Coastal Sediments Sendang Biru Port, East Java, Indonesia. Journal of Physics: Conference Series 2018b, 1093(1), 012002. https://doi.org/10.1088/1742-6596/1093/1/012002

Wijaya, A. R.; Arifani, R. I.; Kusumaningrum, I. K.; Budiasih, E.; Daupor, H.; Hossain, Md. S.; Sanjaya, E. H. Analysis of Fe in Sediment Material Using a Modified Tessier Technique for Detection of Fe-Anthropogenic and Fe-Naturals. IOP Conf. Ser. Mater. Sci. Eng. 2019, 515 (1), 012015. https://doi.org/10.1088/1757-899X/515/1/012015

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