Synthesis, characterization and thermal behaviour of solid-state compounds of 4-methoxybenzoate with lanthanum (III) and trivalent lighter lanthanides

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Érica Alvarenga Crespo Rodrigues
Adriano Buzutti de Siqueira
Elias Yuki Ionashiro
Gilbert Bannach
Massao Ionashiro

Abstract

Solid-state M-4-MeO-Bz compounds, where M stands for trivalent La, Ce, Pr, Nd and Sm and
4-MeO-Bz is 4-methoxybenzoate, have been synthesized. Simultaneous thermogravimetry and differential
thermal analysis (TG-DTA), differential scanning calorimetry (DSC), X-ray powder diffractometry,
infrared spectroscopy and complexometry were used to characterize and to study the thermal behaviour of
these compounds. The results led to information about the composition, dehydration, polymorphic trans-
formation, ligand’s denticity, thermal behaviour and thermal decomposition of the isolated compounds.

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How to Cite
Rodrigues, Érica A. C., de Siqueira, A. B., Ionashiro, E. Y., Bannach, G., & Ionashiro, M. (2006). Synthesis, characterization and thermal behaviour of solid-state compounds of 4-methoxybenzoate with lanthanum (III) and trivalent lighter lanthanides. Eclética Química, 31(1), 21–30. https://doi.org/10.26850/1678-4618eqj.v31.1.2006.p21-30
Section
Original articles

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