Synthesis, characterization and thermal behaviour on solid pyruvates of some bivalent metal ions
PDF

Keywords

bivalent metals
pyruvate
characterization
thermal behaviour

How to Cite

de Siqueira, A. B., de Carvalho, C. T., Ionashiro, E. Y., & Ionashiro, M. (2009). Synthesis, characterization and thermal behaviour on solid pyruvates of some bivalent metal ions. Eclética Química, 34(2), 15–21. https://doi.org/10.26850/1678-4618eqj.v34.2.2009.p15-21

Abstract

Solid state M-L compounds, were M stands for bivalent Mn, Fe, Co, Ni, Cu, Zn and L is pyruvate, have been synthesized. Thermogravimetry and derivative thermogravimetry (TG/DTG), differential scanning calorimetry (DSC), X-Ray powder diffractometry, infrared spectroscopy, elemental analysis, and complexometry were used to characterize and to study the thermal behaviour of these compounds. The results led to information about the composition, dehydration, ligand denticity, and thermal decomposition of the isolated compounds.
https://doi.org/10.26850/1678-4618eqj.v34.2.2009.p15-21
PDF

References

S. Ramamothy, A. Raghavan, V.R. Vijayaraghavan, M. Schutappa, J. Inorg. Chem., 31(1969) 1851.

J. J. Kim, T.E Cummings, J. A. Cok, Anal. Letters, 5 (1972) 703.

V. Veervalur. Raaghavan, D. L. Leussing, J.Indian Chem. Soc., 54(1977) 68.

K.N. Mc. Coy, J. Am. Chem. Soc., 61(1939) 2455.

G. B. Choppin, R. Cannon, Inorg. Chem., 19 (1980) 1889.

W.Brzyska, W. Ożga, Polish J. Chem., 58 (1984) 385.

W.Brzyska, W. Ożga, Polish J. Chem., 59 (1985) 233.

A. B. Siqueira, C. T. de Carvalho, E. C. Rodrigues, E. Y. Ionashiro, G Bannach, M. Ionashiro, Ecl. Quim., 32(4) (2007) 49.

C. N. de Oliveira, M. Ionashiro, C. A. F. Graner, Ecl. Quim., 10 (1985)7.

K. Duczmal, M. Dorowska, E. D. Raczyńska, Vib. Spectrosc. 37 (2005) 77.

H. Hanai, A. Kuwac, Y. Sugawa, K-K. Kunimoto, S. Maeda, J. Molec. Struct., 837 (2007) 101.

S. S. Tavale, L. M. Pant, A. B. Biswas, Acta Cryst., 14 (1961) 1281.

I. A. Petroni, F. L. Fertonani, C. B. Melios, M. Ionashiro, Thermochim. Acta, 400 (2003) 187.

C. Gonzales, J. I. Gutierrez, J. R. Gonzales-Velasco, A. Cid, A. Arranz, J. F. Arranz, J. Therm. Anal. 47 (1996) 93.

D. Czakis-Sulikowska, J. Katuzna, J. Therm. Anal. Cal. 58 (1999) 51.

L. Biernacki, S. Pokrzywnicki, J. Therm. Anal. Cal. 55 (1999) 227.

G. A. El-Shobaki, A. S. Ahmad, A. N. Al-Naomi, H. G. El-Shobaky, J. Therm. Anal. 46 (1996) 1801.

Z. P. Xu, H. C. Zeng, J. Mater. Chem., 8 (1998) 2499.

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Copyright (c) 2018 Eclética Química Journal

Metrics

Metrics Loading ...