Complexes of 4-chlorophenoxyacetates of Nd(III), Gd(III) and Ho(III)
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Abstract
The complexes of 4-chlorophenoxyacetates of Nd(III), Gd(III) and Ho(III) have been synthesized as polycrystalline hydrated solids, and characterized by elemental analysis, spectroscopy, magnetic studies and also by X-ray diffraction and thermogravimetric measurements. The analysed complexes have the following colours: violet for Nd(III), white for Gd(III) and cream for Ho(III) compounds. The carboxylate groups bind as bidentate chelating (Ho) or bridging ligands (Nd, Gd). On heating to 1173K in air the complexes decompose in several steps. At first, they dehydrate in one step to form anhydrous salts, that next decompose to the oxides of respective metals. The gaseous products of their thermal decomposition in nitrogen were also determined and the magnetic susceptibilites were measured over the temperature range of 76-303K and the magnetic moments were calculated. The results show that 4-chlorophenoxyacetates of Nd(III), Gd(III) and Ho(III) are high-spin complexes with weak ligand fields. The solubility value in water at 293K for analysed 4-chlorophenoxyacetates is in the order of 10-4mol/dm3.
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References
S.C. Mojumdar, D. Hudecova, and M. Melnik, Pol. J. Chem., 73 (1999)759
M. McCann, J.F. Cronin, and M. Devereux, Polyhedron, 17(1955)2379
C.N. Rao, and S. Natarajan, Angew, Chem. Int. Ed., 43(2004)1446
E.V. Dikarev, R,G, Gray, and B.Li, Angew. Chem. Int. Ed., 44(2005) 1721
L.Lewellyn, Jim – Ho Lee, Jong-San Chang, and G. Ferey, Angew. Chem. Int. Ed., 45 (2006) 8227
C.J. Kepert, T.J. Prior, and M.J. Rosseinsky, J. Sol. State Chem., 152 (2000) 261
Y. Kim, and D.Y. Yung, Inorg. Chim. Acta, 338(2002)229
Y. Bao-Hui, T. Ming-Liang, and Xiao-Ming Chem., Kord. Chem. Rev., 249(2005)545
E.G. Palacios, and A.J. Monchemius, Hydrometallurgy, 62(2001)135
W.Ferenc, M.Bernat, J. Sarzyński, and B. Paszkowska, Ecl.Quim., São Paolo, 33(1): 7-14, 2008
Beilstein Handbuch der Organischen Chemie, Bd. VI/2, Springer Verlag, Berlin 1942
Franklin and Jones, American Chemical Paint Co, U.S. 2.390, 941, Dec. 11.1945
K.N. Goswami, Z. Krist., 121(5), (1965), 400
Kennard, Colin H.L., Smith, Graham, and White Allan.H., Acta Crystallorg., Sect.B 1981, B37(6), 1317-19
S.Kumar, Vijay, and Rao Leela M., Acta Crystallogr., Sect. B. 1982 B 38(7), 2062
Denis, Janes C. Ramband Jerome, and Ger Offen. 1.906,199, 11 Sept. 1969, Fr. Appl. 16 Feb. 1968
G. Plesch, M. Blahova, J. Kratsmar-Smogrovic, and S. Surka, Z. Naturfors., B, 28, 1973, 521
W.Ferenc, A.Walków-Dziewulska, and S. Kuberski, Chem. Pap., 57(5) (2003) 321-330
W.Ferenc, and B. Bocian, J. Them. Anal. Cal., 74(2003) 521
W.Ferenc, A.Walków-Dziewulska, and J. Sarzyński, J.Serb.Chem.Soc., 70(2005) 1075
W.Ferenc, B. Cristóvão, and J. Sarzyński, J. Them. Anal. Cal., 86(2006) 783
W.Ferenc, A.Walków-Dziewulska, and J. Sarzyński, Ecl. Quim., São Paolo, 31(2) (2006) 17
W.Ferenc, A.Walków-Dziewulska, J. Sarzyński, and B. Paszkowska, Ecl. Quim., São Paolo, 31(3) (2006) 7
W.Ferenc, A.Walków-Dziewulska, J. Sarzyński, B. Paszkowska, Ecl.Quim., São Paolo, 31(4) (2006) 53
K. Stępniak, W.Ferenc, B. Bocian, and T. Lis, Ecl. Quim., São Paolo, 32(3) (2007) 23
W.Ferenc, A.Walków-Dziewulska, J. Sarzyński, and B. Paszkowska, J. Therm. Anal. Cal., 91 (2008) 285
W.Ferenc, B. Cristóvão, J. Sarzyński, and B. Paszkowska, Ecl. Quim., São Paolo, 31(4) (2006) 7
W.Ferenc, A.Walków-Dziewulska, and J. Sarzyński, Acta Chim. Slov. 54(2) (2007) 248
W.Ferenc, K.Czapla, J. Sarzyński, and A. Zwolińska, Ecl. Quim., São Paolo, 33(2) (2008) 7
W.Ferenc, K.Czapla, and J. Sarzyński, Ecl. Quim., São Paolo, 32(3) (2007) 7
B.N. Figgs, and R.S. Nyholm, J. Chem. Soc., (1958) 4190
E. König, Magnetic Properties of Coordination and Organometallic Transition Metal Compounds., Springer Verlag, Berlin, 1966
A. Bartecki, Electronic Spectra of Complex Compounds, Scientific and Technical Publishers, Warsaw, 1987
A.E. Orgel, An Introduction to Transition – Metal Chemistry, Ligand-Field Theory. John Wiley and Sons, New York, 1960
L.J. Bellamy, The Infrared Spectra of Complex Molecules, Chapman L. Hall Ltd, London, 1975
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley and Sons, Toronto, 1997
A. Cross, and A.R. Jones, An Introduction to Practical Infrared Spectroscopy. Butterworths, London, 1969
R.C. Mehrotra and R. Bohra, Metal Carboxylates, Academic Press, London. 1983
G.E. Walfaren, J.Chem. Phys., 40(1964)3249
W.A. Senior, and W.K. Thompson, Nature, 205(1965)170
K. Burger, Coordination Chemistry: Experimental Methods, Akademiai Kiado, Budapest, 1973
R.M. Silverstein and G.C. Bassler, Spectrometric Identification of Organic Compounds, Polish Scientific Publisher, Warsaw, 1970
Y. Kim, and K. Machida, Spectrochim. Acta., 42A(1986)881
M. Mikami, I.Nakagawa, and T. Simanouchi, Spectrochim. Acta, 23A (1967)1037
K. Nakamoto, E. Udovich, and J. Takemoto, J.Am. Chem. Soc., 92 (1970) 3973
M.F. Richardson, W.F. Wagner, and D.E. Sands, Inorg. Chem., 7(1968)2495
R.C. Fay, and R.N. Lowry , Inorg. Nucl. Chem. Lett., 3(1967) 117
W.D. Courier, C.J.L. Lock, and G.Turner, Can. J. Chem., 50 (1972) 1797
A.K. Bridson, Inorganic Spectroscopic Metods, Oxford University Press, New York, 1988
L.M. Harwood, T.D. Claridge, Introduction to Organic Spectroscopy, Oxford University Press, New York, 1999
B.S. Manhas, and A.K. Trikha, J. Indian. Chem. Soc., 59(1982)315
E. Łągiewka, and Z. Bojarski, X-Ray Structural Analysis, Polish Sientific Publisher, Warsaw, 1988
A.V. Nikolaev, A.V. Logvinienko, and L.J. Myachina, Thermal Analysis Vol. 2. Academic Press, New York, 1989
B. Singh, B. V. Agarwala, P.L. Mourya, and A.K. Dey, J. Indian Chem. Soc. 59 (1992)1130
F. Paulik, Speciel Trends in Thermal Analysis, Wiley Chichester, 1995
J. Mroziński, M. Janik, and T. Nowakowski, Scientic Numbers of Silesian Technical University, 119(1988)125
A. Earnshaw, Introduction to Magnetochemistry, Academic Press, London, 1956
E. O’Connor, Progress in Inorganic Chemistry, Wiley, New York, 1982
F.A. Kettle, Inorganic Physical Chemistry, Polish Scientific Publisher, Warsaw, 1999
J. Mroziński, Materials Science, Vol XIV (1988)3
M.Hvastijova, M. Kochout, J. Mroziński, and J. Jäger, Polish J. Chem. 69(1995)852
A.T.baker, A.M.Hammer, and S.E.Livingstone, Transition Metal Chem. 9(1984)423
L.H.Van Vleck, The Theory of Electronic and Magnetic Susceptibilities, Oxford University Press, Oxford, 1932
S.P.Sinha, Systematics and Properties of the Lanthanides, D.Reidel Publishing Company, Dordrecht, 1983
D.J.Karraker, J.Chem.Educ., 47(1970)424