Biosorption of 5G blue reactive dye using waste rice husk
PDF
EPUB

How to Cite

Costa Junior, I. L., Finger, L., Quitaiski, P. P., Neitzke, S. M., Besen, J. V., Correa, M. K., & Mees, J. B. R. (2018). Biosorption of 5G blue reactive dye using waste rice husk. Eclética Química, 43(3), 45–58. https://doi.org/10.26850/1678-4618eqj.v43.3.2018.p45-58

Abstract

In this study, the biosorption was used on the removal of 5G blue dye using rice husk residue. Was evaluated the influence of temperature and pH on the biomass pretreated with H3PO4 and NH4Cl. The tests were realized in batch with previous determination of point of zero charge (PZC). Analytical measurements were performed by UV-Vis spectroscopy.  It was observed a major influence of pH and temperature on the biosorption capacity of the dye, being the highest removal obtained for the condition of pH 2 and temperature of 50 °C. The time for the biomass-dye system to reach equilibrium was around 45 min. The kinetic model of pseudo-first order adequately represented experimental data and had a good correlation coefficient. In the equilibrium study, it was verified that the Langmuir isotherm was the best fit for the experimental data, with a maximum biosorption capacity of 3,84 mg g-1. The use of rice husk as a biosorbent for the removal of reactive blue 5G dye can be considered promising for the abundance of this residue and the observed sorption capacity
https://doi.org/10.26850/1678-4618eqj.v43.3.2018.p45-58
PDF
EPUB

References

Giovanella, R.F., Chiarello, L.M., Barcellos, I.O., and Blosfeld, A.M., Remoção da cor de soluções de corantes reativos com cinza de casca de arroz. Dynamis Revista Tecno-científica. 2(15) (2009) 1-6.

Barakat, M.A., Adsorption and photodegradation of Procion yellow H-EXL dye in textile wastewater over TiO2 suspension. Journal of Hydro-environment Research. 5(2) (2011) 137-142. DOI: 10.1016/j.jher.2010.03.002.

Kimura, I.Y., Gonçalves Jr, A.C., Stolberg, J., Laranjeira, M.C.M., and Fávere, V.T.d., Efeito do ph e do tempo de contato na adsorção de corantes reativos por microesferas de quitosana. Polímeros. 9(3) (1999) 51-57. DOI: 10.1590/s0104-14281999000300010.

Zouboulis, A.I., Loukidou, M.X., and Matis, K.A., Biosorption of toxic metals from aqueous solutions by bacteria strains isolated from metal-polluted soils. Process Biochemistry. 39(8) (2004) 909-916. DOI: 10.1016/s0032-9592(03)00200-0.

Castro, K.C.d., Cossolin, A.S., Reis, H.C.O.d., and Morais, E.B.d., Biosorption of anionic textile dyes from aqueous solution by yeast slurry from brewery. Brazilian Archives of Biology and Technology. 60(0) (2017). DOI: 10.1590/1678-4324-2017160101.

Esposito, A., Pagnanelli, F., Lodi, A., Solisio, C., and Vegliò, F., Biosorption of heavy metals by Sphaerotilus natans: an equilibrium study at different pH and biomass concentrations. Hydrometallurgy. 60(2) (2001) 129-141. DOI: 10.1016/s0304-386x(00)00195-x.

Honorato, A.C., Machado, J.M., Celante, G., Borges, W.G.P., Dragunski, D.C., and Caetano, J., Biossorção de azul de metileno utilizando resíduos agroindustriais. Revista Brasileira de Engenharia Agrícola e Ambiental. 19(7) (2015) 705-710. DOI: 10.1590/1807-1929/agriambi.v19n7p705-710.

Ozsoy, H. and Kumbur, H., Adsorption of Cu(II) ions on cotton boll. Journal of Hazardous Materials. 136(3) (2006) 911-916. DOI: 10.1016/j.jhazmat.2006.01.035.

Gimbert, F., Morin-Crini, N., Renault, F., Badot, P.-M., and Crini, G., Adsorption isotherm models for dye removal by cationized starch-based material in a single component system: Error analysis. Journal of Hazardous Materials. 157(1) (2008) 34-46. DOI: 10.1016/j.jhazmat.2007.12.072.

Liu, Y. and Liu, Y.-J., Biosorption isotherms, kinetics and thermodynamics. Separation and Purification Technology. 61(3) (2008) 229-242. DOI: 10.1016/j.seppur.2007.10.002.

Liu, Y. and Liu, Y.-J., Reply to “Comments on “Biosorption isotherms, kinetics and thermodynamics” review”. Separation and Purification Technology. 63(2) (2008) 250. DOI: 10.1016/j.seppur.2008.07.006.

Kosmulski, M., pH-dependent surface charging and points of zero charge II. Update. Journal of Colloid and Interface Science. 275(1) (2004) 214-224. DOI: 10.1016/j.jcis.2004.02.029.

Lagergren, S., Zur theorie der sogenannten adsorption geloster stoffe. Kungliga Svenska Vetenskapsakademiens Handlingar. 24(4) (1898) 1-38.

Ho, Y.S. and McKay, G., Pseudo-second order model for sorption processes. Process Biochemistry. 34(5) (1999) 451-465. DOI: 10.1016/s0032-9592(98)00112-5.

Yang, X. and Al-Duri, B., Kinetic modeling of liquid-phase adsorption of reactive dyes on activated carbon. Journal of Colloid and Interface Science. 287(1) (2005) 25-34. DOI: 10.1016/j.jcis.2005.01.093.

Radhika, M. and Palanivelu, K., Adsorptive removal of chlorophenols from aqueous solution by low cost adsorbent—Kinetics and isotherm analysis. Journal of Hazardous Materials. 138(1) (2006) 116-124. DOI: 10.1016/j.jhazmat.2006.05.045.

Amuda, O.S., Giwa, A.A., and Bello, I.A., Removal of heavy metal from industrial wastewater using modified activated coconut shell carbon. Biochemical Engineering Journal. 36(2) (2007) 174-181. DOI: 10.1016/j.bej.2007.02.013.

Desta, M.B., Batch Sorption Experiments: Langmuir and Freundlich Isotherm Studies for the Adsorption of Textile Metal Ions onto Teff Straw (Eragrostis tef) Agricultural Waste. Journal of Thermodynamics. 2013(2013) 1-6. DOI: 10.1155/2013/375830.

Ng, C., Losso, J.N., Marshall, W.E., and Rao, R.M., Freundlich adsorption isotherms of agricultural by-product-based powdered activated carbons in a geosmin–water system. Bioresource Technology. 85(2) (2002) 131-135. DOI: 10.1016/s0960-8524(02)00093-7.

Gupta, V.K., Pathania, D., Singh, P., Kumar, A., and Rathore, B.S., Adsorptional removal of methylene blue by guar gum–cerium (IV) tungstate hybrid cationic exchanger. Carbohydrate Polymers. 101(2014) 684-691. DOI: 10.1016/j.carbpol.2013.09.092.

Hameed, B.H., Mahmoud, D.K., and Ahmad, A.L., Equilibrium modeling and kinetic studies on the adsorption of basic dye by a low-cost adsorbent: Coconut (Cocos nucifera) bunch waste. Journal of Hazardous Materials. 158(1) (2008) 65-72. DOI: 10.1016/j.jhazmat.2008.01.034.

Fiorentin, L.D., Trigueros, D.E., Módenes, A.N., Espinoza-Quiñones, F.R., Pereira, N.C., Barros, S.T., and Santos, O.A., Biosorption of reactive blue 5G dye onto drying orange bagasse in batch system: Kinetic and equilibrium modeling. Chemical Engineering Journal. 163(1) (2010) 68-77.

Fagundes-Klen, M.R., Cervelin, P.C., Veit, M.T., da Cunha Gonçalves, G., Bergamasco, R., and da Silva, F.V., Adsorption Kinetics of Blue 5G Dye from Aqueous Solution on Dead Floating Aquatic Macrophyte: Effect of pH, Temperature, and Pretreatment. Water, Air, & Soil Pollution. 223(7) (2012) 4369-4381. DOI: 10.1007/s11270-012-1201-x.

Saeed, A., Sharif, M., and Iqbal, M., Application potential of grapefruit peel as dye sorbent: Kinetics, equilibrium and mechanism of crystal violet adsorption. Journal of Hazardous Materials. 179(1-3) (2010) 564-572. DOI: 10.1016/j.jhazmat.2010.03.041.

Aksu, Z., Equilibrium and kinetic modelling of cadmium(II) biosorption by C. vulgaris in a batch system: effect of temperature. Separation and Purification Technology. 21(3) (2001) 285-294. DOI: 10.1016/s1383-5866(00)00212-4.

Módenes, A.N., Espinoza-Quiñones, F.R., Geraldi, C.A.Q., Manenti, D.R., Trigueros, D.E.G., Oliveira, A.P.d., Borba, C.E., and Kroumov, A.D., Assessment of the banana pseudostem as a low-cost biosorbent for the removal of reactive blue 5G dye. Environmental Technology. 36(22) (2015) 2892-2902. DOI: 10.1080/09593330.2015.1051591.

Sodré, F.F., Lenzi, E., and Costa, A.C.S.d., Utilização de modelos físico-químicos de adsorção no estudo do comportamento do cobre em solos argilosos. Química Nova. 24(3) (2001) 324-330. DOI: 10.1590/s0100-40422001000300008.

Abdelwahab, O., El-Nemr, A., El-Sikaily, A., and Khaled, A., Use of rice husk for adsorption of direct dyes from aqueous solution: A case study of direct F. Scarlet. Egyptian Journal of Aquatic Research. 31(1) (2005) 1-11.

Chowdhury, S. and Saha, T.K., Removal of reactive blue 4 (RB4) onto puffed rice in aqueous solution. International Journal of Advanced Research (IJAR). 4(3) (2016) 927-934.

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Copyright (c) 2018 Eclética Química Journal

Metrics

PDF views
437
Oct 10 '18Oct 13 '18Oct 16 '18Oct 19 '18Oct 22 '18Oct 25 '18Oct 28 '18Oct 31 '18Nov 01 '18Nov 04 '18Nov 07 '186.0
| |
Other format views
21
Jan 2019Jul 2019Jan 2020Jul 2020Jan 2021Jul 2021Jan 2022Jul 2022Jan 2023Jul 2023Jan 2024Jul 2024Jan 2025Jul 2025Jan 202610
|