Determination of trace amounts of selenium in natural spring waters and tea samples by catalytic kinetic spectrophotometry

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Ramazan Gürkan
Nevalnur Zeynep Gürkan

Abstract

In this work, a new kinetic method is described for the determination of trace Se(IV) in natural spring waters and commercial tea samples. The method is based on the activation of Se(IV) onto the indicator reaction in acidic medium. The reaction was monitored using a fixed time approach of 20 min at 680 nm. The variables affecting the reaction rate were evaluated and optimized. The method allows the determination of Se(IV) in the range of 0.0125-1.0 mg L-1 with a detection limit of 3.6 µg L-1. The precision was in range of 0.63-3.15% (as RSD %) with a higher recovery than 98.6%. The method has been found to be selective against matrix effect. The method was applied to the speciation analysis of inorganic Se species present in the selected samples. The method was statistically validated by analysis of two certified samples and comparing the obtained results to those of HG-AAS analysis. Also, the total Se levels of the samples were determined by using both methods after conversion of Se(VI) into Se(IV) in ultrasonic bath in acidic medium for 30 min at 85-90 °C. The results were in good agreement with those of HG-AAS. The Se(VI) level of the samples was calculated from the difference between amounts of total Se and Se(IV).

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How to Cite
Gürkan, R., & Gürkan, N. Z. (2019). Determination of trace amounts of selenium in natural spring waters and tea samples by catalytic kinetic spectrophotometry. Eclética Química, 44(4), 57–72. https://doi.org/10.26850/1678-4618eqj.v44.4.2019.p57-72
Section
Original articles
Author Biography

Ramazan Gürkan, University of Cumhuriyet, Faculty of Sciences, Department of Chemistry, TR-58140, Sivas, Turkey

University of Cumhuriyet, Chemistry/Analytical Chemistry, Prof. Dr.

References

Ochsenkühn-Petropoulou, M., Tsopelas, F., Speciation analysis of selenium using voltammetric techniques, Anal. Chim. Acta 467 (1-2) (2002) 167-178. https://doi.org/10.1016/S0003-2670(02)00091-0.

Lu, C. Y., Yan, X. P., Capillary electrophoresis on-line coupled with hydride generation-atomic fluorescence spectrometry for speciation analysis of selenium, Electrophoresis, 26 (1) (2005) 155-160. https://doi.org/10.1002/elps.200406102.

World Health Organization (WHO), Selenium in drinking-water. WHO Press, World Health Organization, Geneva, Switzerland, 2011. https://www.who.int/water_sanitation_health/dwq/chemicals/selenium.pdf.

Huerta, V. D., Sánchez, M. L. F., Sanz-Medel, A., An attempt to differentiate HPLC-ICP-MS selenium speciation in natural and selenised Agaricus mushrooms using different in natural and selenised Agaricus mushrooms using different, Anal. Bioanal. Chem. 384 (4) (2006) 902-907. https://doi.org/10.1007/s00216-005-0174-7.

Yuan, C., Gao, E., He, B., Jiang, G., Arsenic species and leaching characters in tea (Camellia sinensis), Food Chem. Toxicol. 45 (12) (2007) 2381-2389. https://doi.org//10.1016/j.fct.2007.06.015.

Jha, A., Mann, R. S., Balachandran, R., Tea: A refreshing beverage, Indian Food Ind. 15 (1996) 22-29.

Huang, C., Hu, B., He, M., Duan, J., Organic and inorganic selenium speciation in environmental and biological samples by nanometer-sized materials packed dual-column separation preconcentration on-line coupled with ICP-MS, J. Mass Spectrom. 43 (3) (2008) 336-345. https://doi.org/10.1002/jms.1321.

Altunay, N., Gürkan, R., Güneş, M., Ultrasound assisted extraction and spectrophotometric determination of trace selenium in water, food and vegetable samples, Anal. Methods. 8 (46) (2016) 8208-8218. https://doi.org/10.1039/C6AY02638A.

Ahmed, M. J., Islam, M. T., Nime, M. J., A highly selective and sensitive spectrophotometric method for the determination of selenium using 2-hydroxy-1-napthaldehyde-orthoaminophenol, Anal. Methods. 7 (18) (2015) 7811-7823. https://doi.org/10.1039/C5AY01311A.

Tuzen, M., Saygi, K. O., Soylak, M., Separation and speciation of selenium in food and water samples by the combination of magnesium hydroxide co-precipitation-graphite furnace atomic absorption spectrometric determination, Talanta 71 (2007) 424-429. https://doi.org/10.1016/j.talanta.2006.04.016.

Panhwar, A. H., Tuzen, M., Kazi, T. G., Ultrasonic assisted dispersive liquid-liquid microextraction method based on deep eutectic solvent for speciation, preconcentration and determination of selenium species (IV) and (VI) in water and food samples, Talanta 175 (2017) 352-358. https://doi.org/10.1016/j.talanta.2017.07.063.

Santos, E. J., Oliveira, E., Evaluation of Arsenic and Selenium in Brazilian Soluble Coffee by Inductively Coupled Plasma Optical Emission Spectrometry with Hydride Generation, Brazil. Arch. Biol. Technol. 44 (3) (2001) 233-238. https://doi.org/10.1590/S1516-89132001000300003.

Anthemidis, A. N., Determination of Selenium (IV) in Natural Waters by HG-AAS Using an Integrated Reaction Chamber Gas–Liquid Separator, Spectrosc. Lett. 39 (6) (2006) 699-711. https://doi.org/10.1080/00387010600934519.

Arain, M. A., Khuhawar, M. Y., Bhanger, M. I., Liquid chromatographic determination of selenium in vegetables and tea leaves as 2,1,3-benzoselenaiazole, J. Chem. Soc. Pak. 21 (2) (1999) 137-140. https://www.jcsp.org.pk/ViewByVolume.aspx?v=72&i=VOLUME 21, NO2, JUN 1999.

Yoshida M, Kimura Y, Abe M, Ando T, Tachi H, Fukunaga K. Quantitative evaluation of selenium contained in tea by high performance liquid chromatography, J. Nutr. Sci. Vitaminol. (Tokyo). 47 (3) (2001) 248-252. https://doi.org/10.3177/jnsv.47.248.

Zhou, Q., Lei, M., Li, J., Wang, M., Zhao, D., Xing, A., Zhao, K., Selenium speciation in tea by dispersive liquid-liquid microextraction coupled to high-performance liquid chromatography after derivatization with 2,3-diaminonaphthalene, J. Sep. Sci. 38 (9) (2015) 1577-1583. https://doi.org/10.1002/jssc.201401373.

Zhou, Q., Lei, M., Li, J., Wang, M., Zhao, D., Xing, A., Zhao, K., Selenium speciation in tea by dispersive liquid–liquid microextraction coupled to high-performance liquid chromatography after derivatization with 2,3-diaminonaphthalene, J. Sep. Sci. 38 (9) (2015) 1577-1583. https://doi.org/10.1002/jssc.201401373.

Keyvanfard, M., Sharifian, A., Kinetic spectrophotometric method for the determination of selenium(iv) by its catalytic effect on the reduction of spadns by sulphide in micellar media, J. Anal. Chem. 61 (6) (2006) 596-600. https://doi.org/10.1134/S1061934806060153.

Gürkan, R., Ulusoy, H. I., The investigation of a novel indicator system for trace determination and speciation of selenium in natural water samples by kinetic spectrophotometric detection, Bull. Korean Chem. Soc. 31 (7) (2010) 1907-1914. https://doi.org/10.5012/bkcs.2010.31.7.1907.

Ensafi, A. A., Lemraski, M. S., Highly Sensitive Spectrophotometric Reaction Rate Method for the Determination of Selenium Based on the Catalytic Reduction of Sulfonazo by Sulfide, Anal. Lett. 37 (12) (2004) 2469-2483. https:/doi.org/10.1081/AL-200029374.

Gürkan, R., Ulusoy, H. I., Akçay, M., Bulut, P., A novel indicator system for catalytic spectrophotometric determination and speciation of inorganic selenium species (Se(IV), Se(VI)) at trace levels in natural lake and river water samples, Rare Metals 30 (5) (2011) 477-487. https://doi.org/10.1007/s12598-011-0416-0.

Chen, Y.-H., Zhang, Y.-N., Tiana, F.-S., Determination of selenium via the fluorescence quenching effect of selenium on hemoglobin catalyzed peroxidative reaction, Luminescence 30 (3) (2015) 263-268. https://doi.org/10.1002/bio.2723.

Gurkan, R., Akcay, M., Kinetic spectrophotometric determination of trace amounts of selenium based on the catalytic reduction of maxilon blue-SG by sulfide, Microchem. J. 75 (2003) 39-49. https://doi.org/10.1016/S0026-265X(03)00049-3.

Keyvanfard, M., Kinetic-Spectrophotometric Determination of Trace Amounts of Vanadium (V) Based on its Catalytic Effect on the Oxidation of Victoria Blue B by Potassium Bromate in Micellar Medium, World Appl. Sci. J. 6 (5) (2009) 624-629. https://www.idosi.org/wasj/wasj6(5)/8.pdf.

Temel, N. K., Gürkan, R., A micellar sensitized kinetic method for quantification of low levels of bisphenol A in foodstuffs by spectrophotometry, Anal. Methods 9 (7) (2017) 1190-1200. https://doi.org/10.1039/C6AY03064E.

Martinez-Lozano, C., Perez-Ruiz, T., Tomas, V., Abellan, C., Flow injection spectrophotometric determination of selenium based on the catalyzed reduction of Toluidine Blue in the presence of sulphide ion, Analyst 114 (1989) 715-717. https://doi.org/10.1039/AN9891400715.

Gökmen, I. G., Abdelkader, E., Determination of selenium in biological matrices using a kinetic catalytic method, Analyst 119 (4) (1994) 703-708. https://doi.org/10.1039/AN9941900703.

Ensafi, A. A., Dehaghi, G. B., Kinetic-spectrophotometric determination of trace amounts of selenium with catalytic reduction of gallocyanine by sulfide, Anal. Lett. 28 (2) (1995) 335-347. https://doi.org/10.1080/00032719508000326.

Safavi, A., Afkhami, A., Catalytic spectrophotometric determination of selenium, Anal. Lett. 28 (6) (1995) 1095-1105. https://doi.org/10.1080/00032719508002681.

Safavi, A., Sedghi, H. R., Shams, E., Kinetic spectrophotometric determination of trace amounts of selenium and vanadium, Fresenius J. Anal. Chem. 365 (6) (1999) 504-510. https://doi.org/10.1007/s002160051513.

Chand, V., Prasad, S., Trace determination and chemical speciation of selenium in environmental water samples using catalytic kinetic spectrophotometric method, J. Hazard. Mater. 165 (1-3) (2009) 780-788. https://doi.org/10.1016/j.jhazmat.2008.10.076.

Burstein, S., Reduction of phosphomolybdic acid by compounds possessing conjugated double bonds, Anal. Chem. 25 (3) (1953) 422-424. https://doi.org/10.1021/ac60075a012.

Zarzycki, P. K., Bartoszuk, M. A., Radziwon, A. I., Optimization of TLC detection by phosphomolybdic acid staining for robust quantification of cholesterol and bile acids, JPC-J, Planar Chrom-Modern TLC 19 (107) (2006) 52-57. https://doi.org/10.1556/JPC.19.2006.1.9.

Zarzycki, P. K., Bartoszuk, M. A., Improved TLC detection of prostaglandins by post-run derivatization with phosphomolybdic acid, JPC-J. Planar Chrom-Modern TLC 21 (5) (2008) 387-390. https://doi.org/10.1556/JPC.21.2008.5.12.

Sims, R. P. A., Formation of heteropoly blue by some reduction procedures used in the micro-determination of phosphorous, Analyst 86 (1961) 584-590. https://doi.org/10.1039/AN9618600584.

Theodore, G. T., Determination of aqueous phosphate by ascorbic acid reduction of phosphomolybdic acid, Anal. Chem. 58 (1) (1986) 223- 229. https://doi.org/10.1021/ac00292a054.

Zatar, N. A., Abu-Eid, M. A., Eid, A. F., Spectrophotometric determination of nitrite and nitrate using phosphomolybdenum blue complex, Talanta 50 (4) (1999) 819-826. https://doi.org/10.1016/S0039-9140(99)00152-6.

Sicilia, D., Rubio, S., Perez-Bendito, D., Kinetic determination of antimony(III) based on its accelerating effect on the reduction of 12-phosphomolybdate by ascorbic acid in a micellar medium, Anal. Chem. 64 (13) (1992) 1490-1495. https://doi.org/10.1021/ac00037a031.

Tosi, E. A., Cazzoli, A. F., Tapiz, L. M., Phosphorous in oil. Production of molybdenum blue derivative at ambient temperature using non-carcinogenic reagents, J. Am. Oil Chem. Soc. 75 (1998) 41-44. https://doi.org/10.1007/s11746-998-0007-x.

Nalumansi, I., Mbabazi, J., Ssekaalo, H., Ntale, M., Effect of various reductants on the spectral characteristics of the reduced phosphopolyoxomolybdate anion, and its application to orthophosphate anion quantification in selected Ugandan waters, Int. J. Curr. Trends in Engin. Technol. 1 (2) (2015) 59-66. http://www.ijctet.org/assets/upload/463IJCTET123.pdf.

Shukor, Y., Adam, H., Ithnin, K., Yunus, I., Shamaan, N.A., Syed, M.A., Molybdate reduction to molybdenum blue in microbe proceeds via a phosphomolybdate intermediate, J. Biol. Sci. 7 (8) (2007) 1448-1452. https://doi.org/10.3923/jbs.2007.1448.1452.

Derun, E. M., Kipcak, A. S., Ozdemir, O.D., Piskin, M. B. Cr, Fe and Se Contents of the Turkish Black and Green Teas and the Effect of Lemon Addition, Int. Scholar. Sci. Res. Innov. 6 (11) (2012) 1018-1021. https://publications.waset.org/7515/pdf.