A model for specific interactions of manganese-phthalocyanine in protic media

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Nadir Ana Wiederkehr

Abstract

Extinction coefficients (e) changes of manganese phthalocyanine (Mn-Pc) were studied in different organic solvents and related to solvent polarity scales (Kosower's values (Z), Dimroth's values (ET), donor numbers (DN) and linear solvation energy relationships (LSER) or linear free energy relationships (LFER)), theoretical molecular orbital calculations and ligand/solvent coordination processes in order to predict molecular interaction with the medium and identification of predominant intermolecular forces.

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Wiederkehr, N. A. (1999). A model for specific interactions of manganese-phthalocyanine in protic media. Eclética Química, 24(1), 45–59. https://doi.org/10.26850/1678-4618eqj.v24.1.1999.p45-59
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Original articles

References

ABRAHAM, M.H. Scales of Solute Hydrogen-bonding: Their construction and application to physicochemical and biochemical processes. Chem. Soc. Rev., v.22, p.73-141, 1993.

AGREN, H., MIKKELSEN, K.V. Theory of solvent effects on electronic spectra. J. Mol. Struct., v.234, p.425-30, 1991.

ARNETT, E.M., Solvation energies of organic ions. J. Chem.Educ. (New York), v.62, p.385-91, 1985.

BARRACLOUGH, C.G., MARTIN, R.L., MITRA, S., SHERWOOD, R.C. Paramagnetic anisotropy, electronic structure and ferromagnetism in spin S = 3/2 manganese(II) phthalocyanine. J.Chem.Phys., v.53, p.1638, 1970.

ENGELSMA, G., YAMAMOTO, A., MARKHAM, E., CALVIN, M. The effect of light on oxidation and reduction reactions involving phthalocyanine and etioporphyrin I manganese complexes. J.Phys.Chem., v.66, p.2517-30, 1962.

ERCOLANI, C., FLORIS, B. Metal Phthalocyanine Single-Atom Bridged Dimers in Phthalocyanines, Properties and Applications, VCH Publishers., 1993. v.2.

FAN, F.R., FAULKNER, L.R. Phthalocyanine thim films as semicondutor electrodes. J. Am. Chem. Soc. (Washington), v.101, p.4779-87, 1979.

FISCHER, M.S., TEMPLETON, D.H., ZALKIN, A., CALVIN, M. Structure and chemistry of the porphyrins. The crystal and molecular structure of the monohydrated dipyridinated magnesium phtalocyanin complex. J. Am. Chem. Soc. (Washington), v.93, p.2622-28, 1971.

GOUTERMAN, M. The Porphyrins, New York: Academic Press,1978. v. III, cap.1

GRÄTZEL, M., KALYANASUNDARAM K., THOMAS, J.K. Proton nuclear magnetic resonance and laser photolysis studies of pyrene derivates in aqueous and micellar. J. Amer. Chem. Soc. (Washington), v.96, p.7869-74, 1974.

GRIFFITHS, T.R., PUGH, D.C. Correlations among solvent polarity scales, dielectric constant and dipole moment, and a means to reliable predictions of polarity scale values from current data. Coord. Chem. Reviews (Amsterdan), v.29, p.129-211, 1979.

IONESCU, L.G., ROMANESCO, L.S., NOME, F. Surfactants in solution, Mittal, New York: Plenum Press, 1984.

IONESCU, L.G., TOKUHIRO, T., CZERNIAWSKI, B.J. Formation of micelles of hexadecyltrimethylammonium bromide in water-N,N-dimethylformamide solutions. Bull. Chem. Soc. Japan (Tokio), v.52, p.922-24, 1984.

IONESCU, L.G., WIEDERKEHR, N.A. Interaction of magnesium phthalocyanine with organic solvents. Quimica Nova, v.10, n.3, p.246-48, 1987.

KARWEIK, D.H., WINOGRAD, N. Nitrogen charge distributions in free-base porphyrins, matalloporphyrins, and their reduced analogues observed by x-ray photoelectron spectroscopy. Inorg. Chem. (Washington), v.15, p.2336-42, 1976.

KIRNER, J.F., DOW, W., SCHEIDT, W.R., Molecular steochemistry of two internediate-spin complexes. Iron (II) phthalocyanine and manganeze(II) phthalocyanine. Inorg. Chem. (Washington), v.15, p.1685-90, 1976.

KÖNIG, E., Structural changes accompanying continuous and discontinuous spin-state transitions. Prog. Inorg. Chem. (London), v.35, p.527-619, 1987.

LEVER, A.B.P. Adv. Inorg. Chem. Radiochem., v.7, p.27, 1965.

LEVER, A.B.P., WILSHIRE, J.P., QUAN, S.K. A manganese phthalocyanine-dioxygen molecular adduct. J. Am. Chem. Soc. (Washington), v.101, p.36680-69, 1979.

MARCUS,Y. The properties of organic liquids that are relevant to their use as solvating solvents. Chem. Soc. Rev., v.21, p.409-16, 1993.

MARSHALL, G.C., HIROAKI, H., ZERNER, M.C. Calculated Structures and Electronic Absorption Spectroscopy for Magnesium Phthalocyanine and Its Anion Radical. Inorg. Chem. (Washington), v.34, p.2969-79, 1995.

PREVIATTI, M. 1983. Dissertação (Mestrado) Universidade Federal de Santa Catarina.

PREVITALI, C.M., Pure Appl.Chem., v.67, p.127, 1995.

REICHARDT, C. Solvatochromic Dyes as Solvent Polarity Indicators. Chem. Revi., v.94, p.2319-58, 1994.

RITCHIE, C.D., MEGERLE, G.H. J. Am. Chem.Soc. (Washington), v.88, p.1447, 1967.

SCHAFFER, A.M., GOUTERMAN, M., DAVIDSON, E.R. Porphyrins XXVIII. Extended hückel calculations on metal phthalocyanines and tetrazaporphins. Theoret. Chim. Acta (Berlin), v.30, p.9-30, 1973.

SCHNEIDER, R.L. Properties of Some Organic Solvents. Eastman Organic Chemical Bulletin, v.47, p.1, 1975.

SOUKUP, R.W., SCHMID, R. Metal complexes as color indicators for solvent parameters. J. Chem.Educ. (New York), v.62, p.459-62, 1985.

STILLMAN, M.J., NYOKONG, T. Absorption and Magnetic Circular Dichroism of Phthalocyanines, in Phthalocyanines, Properties and Applications, VCH Publishers, 1993, v.2.

SUPPAN, P. Invited Review: Solvatochromic Shifts. The Influence of the Medium on the Energy of Electronic States. J. Photochem. Photobiology, A: Chemistry, v.59, p.293-330, 1990.

TURRO, N.J. Modern Molecular Photochemistry, New York: University Science Books, 1991.

VINCETT, P.S., VOIGT, E.M., RIECKHOFF, K.E. J.Chem.Phys., v.55, p.4131, 1971.

VOGT, L.H., ZALKIN, A., TEMPLETON, D.H. The crystal and molecular structure of phtalocyanatopyridine-manganese(III)-µ-oxo-phtalocyanatopyridinemanganese(III) dipyridinate. Inorg. Chem. (Washington), v.6, p.1725-30, 1967.

YAMAMOTO, A., PHILLIPS, L.K., CALVIN, M. Coordination of pyridine to phthalocyaninomanganese and etioporphyrin I-manganese complexes. Inorg. Chem. (Washington), v.7, p.847-52, 1968.

WIEDERKEHR, N.A. The aggregation behavior of Zinc-Tetracarboxy-Phthalocyanine and Its Spectral Sensitization on Titanium Dioxide Films. J. Braz. Chem. Soc. (São Paulo), v.7, n.1, p.7-13, 1996.

______. Solubilização e interação de pigmentos organo-metálicos com solventes orgânicos e agentes de superfície. Dissertação (Mestrado), PPGEEMM, Universidade Federal do Rio Grande do Sul.

______. Axial Ligands as Interplanar Spacers in Macrocyclic Solids, JICS, 1998. (submitted).