Abstract
A simple, sensitive and selective spectrophotometric method for the assessment of carbofuranin various formulations and in environmental water samples is described. The method is based on the
coupling of hydrolyzed carbofuran with diazotized dapsone in alkaline medium at 0 – 4° C which gives
orange red colored product having the absorption maximum at 480 nm. The product is stable for 48 h.
Beer’s law is obeyed in the concentration range of 0.1 – 4.0 μg ml -1 . The molar absorptivity and Sandell’s
Sensitivity are 5.0 x 10 4 L mol-1 cm -1 and 4.4 ng cm -2 respectively. The method is highly reproducible
and is confirmed by RSD values (1.144 %). From the recovery studies it is found that this method is
accurate and it can be successfully employed for the determination of carbofuran.
References
R.C. Gupta, Carbofuran toxicity. J Toxicol. Environ.
Health 43 (1994) 383.
R. L. Baron, Carbamate insecticides, In Handbook of
Pesticide Toxicology, Hayes, W. J. Jr. , E. R Laws Jr, Eds,
Academic Press, New York, 3 ,1991.
U.S. Department of Agriculture, Soil Conservation
Service, SCS/ARS/CES Pesticide Properties Database:
Version 2.0 (Summary). USDA - Soil Conservation Service,
Syracuse, New York, (1990).
P. H. Howard, Handbook of Environmental Fate and
Exposure Data for Organic Chemicals: Pesticides. Lewis
Publishers, Chelsea, MI, 3 ,1991.
R.P. Richards, L.W. Kramer, D.B. Baker, K.A. Krieger,
Nature 327 (1987) 129.
D.T. Waite, R Grover, N.D. Wescott, H. Sommerstand, L.
Karr, Environ. Toxicol. Chem. 11 (1992) 741.
N. W. Erwin, Journal of Pesticide Reform 11(4) (1991) 15.
C. H. Soler, F. Brett, J. Ambrose, J. K. Manes, Y.J. Pico,
Anal. Chim. Acta 571(1) (2006) 1.
Pang, Guo-Fang Liu, Yong-Ming Fan, Chun-Lin Zhang, Jin-
Jie Cao,Yan-Zhong Li, Xue-Min Li, Zeng-Yin Wu, Yan-PingGuo, Tong-Tong, Anal. Bioanal. Chem. 384(6), (2006), 1366.
F. Hernandez, O. J Pozo, J. V. Sancho, L. Bijlsma, M.
Barreda, E. Pitarch, Spain Journal of Chromatography A
(2) (2006) 242.
T. Kawamoto, N. Makihata, Analytical Sciences 19
(2003) 1605.
E. S. Petropoulou, E. T. Gikas, P. S. Anthony, A, Journal
of Chromatography A 1115 (1-2) (2006) 271.
L. Wong, Fisher F M, J. Agric Food Chem 23 (1975) 315.
R .F. Cook, R. P. Stanovick, C. C. Cassil, J. Agric Food
Chem. 17 (1969) 277.
L. I. Bulter, L .M.McDonough, J. Agric. Food Chem. 54
(1971) 1357.
C. H .Van Middelem, H. A. Moye, M. J .Janes, J. Agric
Food Chem. 19 (1971) 459.
O. Agrawal, V. K. Gupta, J. Microchemical 62(1) (1999)
M.C. Bowman, M. Beroza, J. Assoc. Off Anal Chem. 50
(1967) 926.
L. I. Butler, L. M. McDonough, J. Agric. Food Chem. 16
(1968) 403.
C. C. Cassil, R. P. Stanovick, C. C. Cassil, Res. Rev.
(1969) 63.
J. N Seiber, J. Agric Food Chem. 20 (1972) 443.
I. H. Williams, M. J. Brown, J. Agric Food Chem. 21
(1973) 399.
R. W. Frei, J. F. Lawrence, J. Hope, R. M. Cassidy, J.
Chromatogr. Sci. 12 (1974) 40.
J. F. Lawrence, R. Leduc, J. Agric Food Chem. 25 (1977)
Z. Renato, D.M. Rogério, P. V. Cristiane , Pest
Mangement Science 56 (9) (2000) 804.
J. R. Rangaswamy, Y. N. Vijayashankar, S. R Prabhakar,
J. Assoc. Anal. Chem. 59 (1976) 1276.
S. K. Handa, A. K. Dikshit, J. Assoc. Anal. Chem. 61
(1978) 1513.
K. M. Appaiah, R. Ramakrishna, K. R. Subba Rao, K. V.
Nagaraja, O.P. Kapur, J.Food Sci. Technol. 19 (1982) 211.
V. Harikrishna, B. Prasad, N. V. S. Naidu, J. Indian
Council of Chemists 2 (2003) 20.
C. V. Rajeswari, P. R. Naidu, J. Food Sci. Technol. 23
(1986) 101.
R. Kumar, C. B. Sharma, Anal. Lett. 20 (1987) 777.
D. V. Naidu, P. R. Naidu, Proc. Indian Natl.Sci.Acad. 56
(1990) 203.
A. Salvador, Z. A. Debenzo, M. Dela Guardia, J. Micro
Chem. 42(1990) 187.
S. K. Handa, J. Assoc Off Anal. Chem. 63(1980) 200.
C. V. Rajeswari, A. V. Naidu, P. R .Naidu, Curr. Sci. 53
(15) (1984) 800.
Alvarez-Rodriguez A, Monferrer-Pns Li, Esteve-Romero
J, Garcia-M. C. Alverez-Coque, G.Ramis-Ramus, Analyst 122
(1997) 459.
M. S. Mithyantha, N. G .Perur, Curr. Sci. 43 (1974) 18.
R. Zenalla, R. M. Dalloago, E. M .M. Flores, A.F.
Maritins, Analytical Letters 32(3) (1999) 593.
R. Kesart, J. V. Das, V. K. Gupta, J. Ind. Chem. Soc.
(3) (1998) 181
M.R. Jan, J. Shah , H. Khan , Chemosphere 52(9) (2003)
O. Bhargavi, K. Kiran, K. Suvardhan, D. Rekha, K.
Janardhanam, P. Chiranjeevi, E-Journal of Chemistry 3(11)
(2006) 68.

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